U S Government--post Office Rion, SC 29132 Phone : (803) 635-3711 Business Category Post Offices Government Offices & Public Schools U S Government 2143 Rion Rd Winnsboro, SC 29180 Phone : (803) 635-3711 Business Category Government Offices & Public Schools Post Office - Rion 243 Rion Rd Rion, SC 29132 Phone : (803) 635-3711 Post Office - Rion Business Category Post Offices Toll-Free           (800) ASK-USPS